课题组

◆近期发表的论文

2024年

71. J.H. Wang, Y.P. Zhou, Y. Ying, J.F. Feng, Z.P. Wang, G.F. Cai*, A Reversible MnO2 Deposition-Enabled Multicolor Electrochromic Device with Efficient Tunability of Ultraviolet-Visible Light. Small, 2024, 2310229 https://doi.org/10.1002/smll.202310229.

70. J.H. Wang, Y. Ying, Y.P. Zhou, S.S. Jia, F. Zhu, O.G. Schmidt, G.F. Cai*, Electrolyte design for reversible metal electrodeposition-based electrochromic energy-saving devices. APL Energy, 2024, 2, 011501 https://doi.org/10.1063/5.0185647.

69. J.F Feng, X.Y. Wang, Y. Luo, J.H. Wang, Z.P. Wang, C.Y. Wei, G.F. Cai*, Transparent-to-Brown-Black Patterned Electrochromic Metal-Organic Frameworks. ACS Appl. Mater. Interfaces, 2024, 16, 1, 1170–1178.

2023年

68. J.J. Huang, S.Y. Zhang, Q. Qin, Z.P. Wang*, G.F. Cai*, Designing V2O5/MXene van der Waals heterostructure for complementary electrochromic dual-ion capacitor, Chemical Engineering Journal, 2023, 476, 146626.

67. C. Y. Jiang, R. Ge, C. C. Bian, L. R. Chen, X. R. Wang, Y. Zheng, G. Xu, G. F. Cai*, X. D. Xiao*, Multicolor of Inorganic Electrochromic Materials: Status, Challenge, and Prospects, Nanoscale, 2023, 15, 15450-15471

66. C. C. Bian, J. H. Wang, H. H. Liu, Y. Yan, P. Zhang, W. L. Yang, S. S. Jia, X. D. Guo, G. F. Cai*, Comlementary multicolor electrochromic devices based on the porous tin oxide nanosheet scaffold, Nano Research, 2023, https://doi.org/10.1007/s12274-023-6103-2.

65. J. F. Feng, Y. Luo, X. Y. Wang, G. F. Cai*, R. Gao*, A Large‐Area Patterned Hydrogen‐Bonded Organic Framework Electrochromic Film and Device. Small, 2304691.

64. X. R. Tong, Jinhui Wang, Ping Zhang, Pengyang Lei, Yi Gao, Ruirui Ren, Siyu Zhang, Rui Zhu*, Guofa Cai*, Insight into the structure–activity relationship in electrochromism of WO3 with rational internal cavities for broadband tunable smart windows, Chemical Engineering Journal, 2023, 470, 144130.

63. P. Zhang, X. R. Tong, Y. Gao, Z. Y. Qian, R. R. Ren, C. C. Bian, J. H. Wang*, G. F. Cai*, A Sensing and Stretchable Polymer-dispersed Liquid Crystal Device Based on Spiderweb-Inspired Silver Nanowires-Micromesh Transparent Electrode, Advanced Functional Materials, 2023, 202303270.

62. H. H. Liu, Y. M. Zhang, P. Y. Lei, J. F. Feng, S. Jia, J. J. Huang, C. Y. Hu, C. C. Bian, G. F. Cai*, Selective Electrochromic Regulation for Near Infrared and Visible-Light via Porous Tungsten Oxide Core/Shell Architecture, ACS Applied Materials & Interfaces, 2023, https://doi.org/10.1021/acsami.3c01742.

61. R. R. Ren, S. Y. Liu, Y. Gao, P. Y. Lei, J. H. Wang, X. R. Tong, P. Zhang, Z. P. Wang*, G. F. Cai*, Tunable interaction between Zn2+ and superstructured Nb18W16O93 bimetallic oxide for multistep tinted electrochromic device, ACS Energy Letters, 2023, 8, 2300-2307.

60. S. Y. Liu, C. Y. Wei, H. Wang, W. L. Yang, J. Zhang*, Z. P. Wang, W. L. Zhao, P. S. Lee,* G. F. Cai*, Processable nanoarchitectonics of two-dimensional metallo-supramolecular polymer for electrochromic energy storage devices with high coloration efficiency and stability, Nano Energy, 2023, 110, 108337.

59. J. H. Wang, R. Zhu, Y. Gao, Y. Jia*, G. F. Cai*, Unveiling the Multistep Electrochemical Desorption Mechanism of Cubic NiO Films for Transmissive-to-Black Electrochromic Energy Storage Devices, J. Phys. Chem. Lett., 2023, 14, 2284-2291.

被《The Journal of Physical Chemistry Letters》作为封面报道

58. Y. Gao, P. Y. Lei, S. Y. Zhang, H. H. Liu, C. Y. Hu, Z. Kou, J. H. Wang*, G. F. Cai*, Layer-Stacked NiO Nanowire/Nanosheet Homostructure for Electrochromic Smart Windows with Ultra-Large Optical Modulation, Nanoscale, 2023, https://doi.org/10.1039/D3NR01211E.

57. Z. Kou, J. H. Wang, X. R. Tong, P. Y. Lei, Y. Gao, S. Y. Zhang, X. P. Cui, S. X. Wu*, G. F. Cai*, Multi-functional electrochromic energy storage smart window powered by CZTSSe solar cell for intelligent managing solar radiation of building, Solar Energy Materials and Solar Cells, 2023, 254, 112273.

56. P. Y. Lei, J. H. Wang, Y. Gao, C. Y. Hu, S. Y. Zhang, X. R. Tong, Z. P. Wang, Y. H. Gao*, G. F. Cai*, An Electrochromic Nickel Phosphate Film for Large-Area Smart Window with Ultra-Large Optical Modulation, Nano-Micro Letters, 2023, 15, 34.

55. S. Y. Zhang, P. Y. Lei, J. J. Fu, X. R. Tong, Z. P. Wang*, G. F. Cai*, Solution-processable multicolor TiO2/polyaniline nanocomposite for integrated bifunctional electrochromic energy storage device, Applied Surface Science, 2023, 607, 155015.

54. S. S. Liang, S. J. Wang, Z. H. Wu, B. Wen, G. F. Cai, X. H. Jiang, G. G. Huang, C. G. Li, Y. L. Zhao, Z. L. Du*, Interfacial Charge Modulation: An Efficient Strategy for Stable Blue Quantum-Dot Light-Emitting Diodes, Advanced Optical Materials 2023, 11, 2201802.

2022年

53. G.F. Cai,* R. Zhu, S.Y. Liu, J.H. Wang, C.Y. Wei, Kent J. Grifth, Y. Jia, and P. S. Lee*, Tunable Intracrystal Cavity in Tungsten Bronze-Like   Bimetallic Oxides for Electrochromic Energy Storage, Advanced Energy Materials, 2022, 12, 2103106.

52. Y. Zhong, J. h. Liang, B. L. Zhang, F. M. Wang, W. q. Huang, G.F. Cai, C. Zhang, Y. Xin, B. h. Chen, X. He*，Highly stable, stretchable, and versatile electrodes by coupling of NiCoS nanosheets with metallic networks for flexible electronics, Nanoscale, 2022, 14, 8172-8182.

2021年

51. T.X. Zhu, J.Q. Xiong, J.W. Chen, X.R. Zhou, G.F. Cai, Y.K. Lai*, and P. S. Lee* Flexible electrochromic fiber with rapid color switching and high optical modulation. Nano Res. (2021).

50. P.Y. Lei, J.H. Wang, P. Zhang, S.Y. Liu, S.Y. Zhang, Y.H. Gao*, J.P. Tu, G.F. Cai*, J. Mater. Chem. C, 2021, 9, 14378.

49. S. Y. Liu, P. Zhang, J. J. Fu, C. Y. Wei*, G. F. Cai* A Mini-Review:  Pyridyl-Based Coordination Polymers for Energy Efficient Electrochromic Application. Front. Energy Res. 2021, 9, 620203.

48. X. Han, R. X. Xu, B. W. Sun, J. Xu, W. Hong, G. F. Cai*, K. Qian*. Conductive Silver Grid Electrode for Flexible and Transparent Memristor Applications. Adv. Electron. Mater. 2021, 7, 2000948.

47. X. He*, Z. H. Liu, G. Z. Shen, X. He, J. H. Liang, Y. Zhong, T. L. Liang, J. He, Y.  Xin, C. Zhang, D. D. Ye, G. F. Cai*. Microstructured capacitive sensor with broad detection range and long-term stability for human activity detection. npj flexible electronics 2021, 5, 17.

2020年

46. G. F. Cai, P. Cui, W.X. Shi, Samuel Morris, S.N. Lou, J.W. Chen, J.H. Ciou, Vinod K Paidi, Kug-Seung Lee, S.Z. Li and P.S. Lee, One-dimensional π-d conjugated coordination polymer for electrochromic energy storage device with exceptionally high performance. Advanced Science, 2020, 7，1903109.

45.G. F. Cai, J.W. Chen, J.Q. Xiong, A.L.-S. Eh, J.X. Wang, Masayoshi Higuchi, and Pooi See Lee, Molecular level assembly for high performance flexible electrochromic energy storage devices. ACS Energy Letters, 2020, 5, 1159−1166,

44. X. He, J.Y. Liu, S.R. Zhao, Y. Zhong, B.H. Chen, C. Zhang, W.J. Yang, M. Chen, Y. Xin, M.X. Song, G. F.  Cai, Constructed AgNW@Bi/Al core-shell nano-architectures for high-performance flexible and transparent energy storage device. Nanoscale, 2020, 10, 2040-3372.

43. A.L.-S. Eh, G.W. Chen, Shu Hearn Yu, Gurunathan Thangavel, X.R. Zhou, G. F.  Cai, S.H.Li, Daniel H. C. Chua, P.S. Lee, A quasi-solid-state tristate reversible electrochemical mirror device with enhanced stability. Advanced Science, 2020, 5, 2198-3844.

2019年

42. G. F. Cai, J.H. Ciou, Y.Z. Liu, Y. Jiang, P.S. Lee, Leaf-inspired multiresponsive MXene-based actuator for programmable smart devices. Science Advance, 2019, 5, 7956.

41. K. Parida, G.Thangavel, G. F. Cai, X. Zhou, S. Park, J. Xiong, P. S. Lee, Extremely stretchable and self-healing conductor based on thermoplastic elastomer for all-three-dimensional printed triboelectric nanogenerator. Nature Communications， 2019, 10, 2158.（ESI高被引论文）

40.  F. X. Chen, Y. J. Mai, Q. N. Xiao, G.F. Cai, L. Y. Zhang, C. S. Liu, X. H. Jie, Three-dimensional graphene nanosheet films towards high performance solid lubricants. Applied Surface Science, 2019, 467–468, 30–36.

2018年

39. G. F. Cai, X. Cheng, M. Layani, A. W. M. Tan, S. H. Li, A. L.S. Eh, D.C. Gao, S. Magdassi, and P.S. Lee, Direct inkjet-patterning of energy efficient flexible electrochromics, Nano Energy, 2018, 49, 147–154.

38. G. F. Cai, J.X. Wang, A.L.-S. Eh, J.W. Chen, K. Qian, J. Q. Xiong, G. Thangavel, P.S. Lee, Diphylleia Grayi Inspired Stretchable Hydrochromics with Large Optical Modulation in Visible-Near Infrared Region, ACS Appl. Mater. Interfaces, 2018, 10, 37685–37693.

37. G. F. Cai, S. Park, X. Cheng, A. L-S. Eh, P. S. Lee, Inkjet-printed metal oxide nanoparticles on elastomer for strain-adaptive transmissive electrochromic energy storage systems. Science and Technology of Advanced Materials, 2018, 19, 759–770.

36. J.X. Wang, G. F. Cai, S.H. Li, D. C. Gao, J.X. Xiong, P.S. Lee, Printable Superelastic Conductors with Extreme Stretchability and Robust Cycling Endurance Enabled by Liquid-Metal Particles. Advanced Materials, 2018. 1706157-n/a.

35. Y. J. Mai, F. X. Chen, M. P. Zhou, Q. N. Xiao, G. F. Cai, X. H. Jie, Anchored graphene nanosheet films towards high performance solid lubricants. Materials and Design, 2018, 160, 861–869.

2017年

34. G. F. Cai, P. Darmawan, X. Cheng, P.S. Lee, Inkjet Printed Large Area Multifunctional Smart Windows. Advanced Energy Materials, 2017, 7, 1602598.

被《Advanced Energy Materials》作为扉页报道

33. G. F. Cai, J. X. Wang, M.-F. Lin, J. W. Chen, M. Q. Cui, K. Qian, S. H. Li, P. Cui, P. S. Lee, A semitransparent snake-like tactile and olfactory sensor with reversible stretchable properties. NPG Asia Materials. 2017, 9, e437.

32. G. F. Cai, J.X. Wang, K. Qian, J.W. Chen, S.H. Li, P.S. Lee, Extremely stretchable strain sensors based on conductive self-healing dynamic cross-links hydrogels for human-motion detection, Advanced Science, 2017, 4, 1600190.（ESI高被引论文）

被《Advanced Science》作为封面报道

被《materialsviewschina》后续报道 http://www.materialsviewschina.com/2016/09/22802/

31. G. F. Cai, A. L-S. Eh, L. Ji, P. S. Lee, Recent Advances in Electrochromic Smart Fenestration. Advanced Sustainable Systems. 2017, 1700074.

30. K. Qian, R. Y.Tay, M.-F. Lin, J.W. Chen, H. K. Li, J.J. Lin, J.X. Wang, G.F. Cai, V. C. Nguyen, E. H. T. Teo, T. P. Chen, P. S. Lee, Direct Observation of Indium Conductive Filaments in Transparent, Flexible, and Transferable Resistive Switching Memory. ACS Nano,  2017，11, 1712–1718.

29. A. L.-S. Eh, M.-F. Lin, M. Q. Cui, G. F. Cai,  P. S. Lee, Copper-based reversible electrochemical mirror device with switchability between transparent, blue, and mirror states, Journal of Materials Chemistry C, 2017, 5, 6547-6554 .

28. Y. Zhan,  J. M. R. Tan,  X. Cheng,  A. W. M. Tan, G. F. Cai,  J.W. Chen,  V.P. Kumar,  S. Magdassi,  P. S. Lee, Ti-doped WO3 synthesized by a facile wet bath method for improved electrochromism, Journal of Materials Chemistry C, 2017, DOI:10.1039/C7TC02456H.

27. P. Cui, K. Parida, M.-F. Lin, J.Q. Xiong, G. F. Cai,   P. S. Lee, Transparent, Flexible Cellulose Nanofibril–Phosphorene Hybrid Paper as Triboelectric Nanogenerator. Advanced Materials Interfaces, 2017, 1700651.

2016年

26.  G. F. Cai,  P. Darmawan, M. Cui, J.X. Wang, J.W. Chen, S. Magdassi, P.S. Lee, Highly Stable Transparent Conductive Silver Grid/PEDOT:PSS Electrodes for Integrated Bifunctional Flexible Electrochromic Supercapacitors, Advanced Energy Materials, 2016,  6, 1501882. （ESI高被引论文）

25. G. F. Cai, M.Q. Cui, V.P. Kumar, P. Darmawan, J.X. Wang, X. Wang, A.L.-S. Eh, K. Qian, P.S. Lee, Ultra-large optical modulation of electrochromic porous WO3 film and the local monitoring of redox activity, Chemical Science, 2016, 7, 1373-1382.

24. G. F. Cai, J. X. Wang, P. S. Lee, Next-Generation Multifunctional Electrochromic Devices. Accounts of Chemical Research, 2016, 49, 1469-1476. （ESI高被引论文）

23. G. F. Cai, P. Darmawan, M.Q. Cui, J.W. Chen, X. Wang, A.L.-S. Eh, Magdassi, P.S. Lee, Inkjet-printed all solid-state electrochromic devices based on NiO/WO3 nanoparticle complementary electrodes, Nanoscale, 2016, 8, 348-357.

被收录为2015-2016 Nanoscale热点文章

22. J.X. Wang, C.Y. Yan , G. F. Cai, M.Q. Cui, A. L.-S Eh , P. S. Lee, Extremely Stretchable Electroluminescent Devices with Ionic Conductors，Advanced Materials, 2016, 28, 4490–4496.

被《Advanced Materials》作为扉页报道

Adv. Mater. 2016, Volume 28, Issue 22.

21.  K. Qian, R. Y. Tay, V. C. Nguyen, J. X. Wang, G. F. Cai, T. P. Chen, E. H. T. Teo, P. S. Lee，Hexagonal Boron Nitride Thin Film for Flexible Resistive Memory Applications, Advanced Functional Materials, 2016, 26, 2176–2184.

20. H. Z. Li, J. W. Chen, M. Q. Cui, G. F. Cai, A. L.-S. Eh, P. S. Lee, H. Z. Wang, Q. H. Zhang, Y.G. Li, Spray coated ultrathin films from aqueous tungsten molybdenum oxide nanoparticle ink for high contrast electrochromic applications, Journal of Materials Chemistry C, 2016,4, 33-38.

19. S.H. Li, J.W. Chen, M.Q. Cui, G. F. Cai, J.X. Wang, P. Cui, X.F. Gong, P. S. Lee, A High-Performance Lithium-Ion Capacitor Based on 2D Nanosheet Materials, Small, 2016, 10.1002/smll.201602893.

被《small》作为扉页报道

18. K Qian, G.F. Cai, V. C. Nguyen, T. P. Chen, P. S. Lee, Direct Observation of Conducting Filaments in Tungsten Oxide Based Transparent Resistive Switching Memory, ACS Appl. Mater. Interfaces, 2016, 8, 27885–27891.

2015年

17. G. F. Cai, X. Wang, M. Cui, P. Darmawan, J.X. Wang, A.L.-S. Eh, P.S. Lee, Electrochromo-supercapacitor based on direct growth of NiO nanoparticles, Nano Energy, 2015, 12, 258-267.（ESI高被引论文）

2014年

16. G. F. Cai, J. P. Tu, D. Zhou, L. Li, . H. Zhang, X. L.Wang, C. D. Gu, Constructed TiO2/NiO Core/Shell Nanorod Array for Efficient Electrochromic Application, The Journal of Physical Chemistry C, 2014, 118, 6690-6696.

15. G. F. Cai, J. P. Tu, D. Zhou, X. L.Wang, C. D. Gu, Growth of vertically aligned hierarchical WO3 nano-architecture arrays on transparent conducting substrates with outstanding electrochromic performance. Solar Energy Materials and Solar Cells, 2014, 124, 103-110.

14. G. F. Cai, J. P. Tu, D. Zhou, J. H. Zhang, X. L.Wang, C. D. Gu, Dual electrochromic film based on WO3@polyaniline core/shell nanowire array. Solar Energy Materials and Solar Cells, 2014, 122, 51-58.

13. G. F. Cai, J. P. Tu, D. Zhou, L. Li, J. H. Zhang, X. L.Wang, C. D. Gu, The direct growth of a WO3 nanosheet array on a transparent conducting substrate for highly efficient electrochromic and electrocatalytic applications, CrystEngComm, 2014, 16, 6866-6872.

被《CrystEngComm》作为封面报道

CrystEngComm 2014, Volume 16, Issue 30.

12. J. H. Zhang, G. F. Cai, D. Zhou, H. Tang, X. L.Wang, C. D. Gu, J. P. Tu, Co-doped NiO nanoflake array films with enhanced electrochromic properties, Journal of Materials Chemistry C, 2014,  2, 7013-7021.

11. L. Li, Y.Q. Zhang, X.Y. Liu, S.J. Shi, X.Y. Zhao, H. Zhang, X. Ge, G.F. Cai, C.D. Gu, X.L. Wang, J.P. Tu. One-dimension MnCo2O4 nanowire arrays for electrochemical energy storage, Electrochimica Acta, 2014, 116: 467-474. （ESI高被引论文）

2013 年

10.  G. F. Cai, J. P. Tu, C. D. Gu, J. H. Zhang, J. Chen, D. Zhou, S. J. Shi., X. L.Wang, One-step fabrication of nanostructured NiO films from deep eutectic solvent with enhanced electrochromic performance. Journal of Materials Chemistry A, 2013, 1, 4286-4292.

9. G. F. Cai, D. Zhou, Q. Q. Xiong, J. H. Zhang, X. L.Wang, C. D. Gu, J. P. Tu, Efficient electrochromic materials based on TiO2@WO3 core/shell nanorod arrays. Solar Energy Materials and Solar Cells, 2013, 117, 231-238.

8. G. F. Cai, C. D. Gu, J. Zhang, P. C. Liu, X. L.Wang, J. P. Tu, Ultra fast electrochromic switching of nanostructured NiO films electrodeposited from choline chloride-based ionic liquid. Electrochimica Acta, 2013, 87, 341-347.

7. G. F. Cai, J. P. Tu, D. Zhou, J. H. Zhang, Q. Q. Xiong, X. Zhao, X. L.Wang, C. D. Gu, Multicolor Electrochromic Film Based on TiO2@Polyaniline Core/Shell Nanorod Array. The Journal of Physical Chemistry C, 2013, 118, 6690-6696.

6. G. F. Cai, X. L.Wang, D. Zhou, J. H. Zhang Q. Q. Xiong, C. D. Gu, J. P. Tu, Hierarchical structure Ti-doped WO3 film with improved electrochromism in visible-infrared region. RSC Advances, 2013, 3, 6896-6905.

5. J. Zhang,; J. P. Tu, G. F. Cai,  G. H. Du, X. L.Wang, P. C. Liu, Enhanced electrochromic performance of highly ordered, macroporous WO3 arrays electrodeposited using polystyrene colloidal crystals as template. Electrochimica Acta, 2013, 99, 1-8.

4. J. Zhang,; J. P. Tu,  G. H. Du, Z. M. Dong, Y. S. Wu, L. Chang, D. Xie, G. F. Cai, X. L.Wang, Ultra-thin WO3 nanorod embedded polyaniline composite thin film: Synthesis and electrochromic characteristics. Solar Energy Materials and Solar Cells, 2013, 114, 31-37.

2012 年

3. G. F. Cai, J. P. Tu, J. Zhang, Y. J. Mai; Y. Lu, C. D. Gu, X. L.Wang, An efficient route to a porous NiO/reduced graphene oxide hybrid film with highly improved electrochromic properties. Nanoscale, 2012, 4, 5724-5730.

2. G. F. Cai, J. Liao H. J. Zhang, S. X. Shao, B. S. Liu, X. J. Zhao, The synthesis, characterization, photocatalytic evaluation and deactivation behavior of sheet-like nano titania. Journal of Wuhan University of Technology-Materials Science Edition, 2012, 27, 857-860.

2009 年

1. B. S. Liu, X. L. Wang, G. F. Cai,  L. P. Wen, Y. B. Song, X. J. Zhao, Low temperature fabrication of V-doped TiO2 nanoparticles, structure and photocatalytic studies. Journal of Hazardous Materials, 2009, 169 (1–3), 1112-1118.

◆授权专利

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1	铌钨双金属氧化物电致变色纳米材料的制备方法和应用	ZL 2021 1 1061996.3	蔡国发
2	一种金属-有机框架材料、薄膜及其制备方法和应用	ZI 2022 1 1258343.9	冯吉飞；蔡国发